Once connected, a deal or contact in Zoho CRM can generate the matching customer and invoice records in Zoho Books without someone re-typing the details, and invoice or payment status can flow back into CRM so a sales rep can see it without logging into Books at all. It's a genuinely useful setup wizard, not a manual export process, and it's the right starting point for a business running both products with a fairly standard sales-to-invoice flow.
The connection is one Books organization to one CRM organization. If your business runs multiple Books organizations, say for separate entities or regions, you can only link one of them through the native integration at a time. And it syncs the standard fields and modules Zoho ships by default; anything you've customized, a renamed module, a custom field tracking something specific to your business, doesn't automatically carry across.